low pressure

The dataset contains results from application of a mid-infrared frequency comb-based Fourier transform spectrometer to measure high-resolution spectra of plasmas containing hydrogen, nitrogen, and a carbon source in the 2800 – 3400 cm–1 range. The spectrally broadband and high-resolution capabilities of this technique enable quantum-state-resolved spectroscopy of multiple plasma-generated species simultaneously, including CH4, C2H2, C2H6, NH3, and HCN, providing detailed information beyond the limitations of current methods.

Plasma-activated chemical transformations promise the efficient synthesis of salient chemical products. However, the reaction pathways that lead to desirable products are often unknown, and key quantum-state-resolved information regarding the involved molecular species is lacking. Here we use quantum cascade laser dual-comb spectroscopy (QCL-DCS) to probe plasma-activated NH3 generation with rotational and vibrational state resolution, quantifying state-specific number densities via broadband spectral analysis.

This data set contains the data shown in the corresponding publication in Applied Physics Letters (https://doi.org/10.1063/5.0160303). This publication presents a benchmark of THz absorption spectroscopy against a more established method. Atomic oxygen densities were measured with THz absorption spectroscopy and compared to those obtained from picosecond (ps) two-photon absorption laser induced fluorescence (TALIF) measurements on the same capacitively coupled radio frequency oxygen discharge.

Laser absorption spectroscopy (LAS) was applied to investigate a low pressure DC-pulsed discharge in N2-H2 gas mixtures with addition of CH4 or O2. The discharge was maintained in an industrial-scale, active screen plasma nitrocarburizing (ASPNC) reactor with a steel active screen (AS). Spectroscopic lines of CH4, NH3, HCN, CO and H2O were recorded. The dataset contains the species densities for different gas mixtures.

The dataset contains the data presented in the paper introducing the FEDM (Finite Element Discharge Modelling) code. The FEDM code was developed using the open-source computing platform FEniCS (https://fenicsproject.org). Building on FEniCS, the FEDM code utilises the finite element method to solve partial differential equations. It extends FEniCS with features that allow the automated implementation and numerical solution of fully-coupled fluid-Poisson models, including an arbitrary number of particle balance equations.

The electron swarm transport coefficients (bulk drift velocity, bulk longitudinal component of the diffusion tensor, and effective ionization frequency) in CO are investigated for a wide range of the reduced electric field by means of measurements and kinetic calculations. The set of data contains results of measurements in a scanning drift tube apparatus under time-of-flight conditions as well as of kinetic swarm calculations using solutions of the electron Boltzmann equation and Monte Carlo simulations.

This data set contains the data shown in the corresponding publication in Plasma Sources Science and Technology (https://doi.org/10.1088/1361-6595/acb815). This publication presents the first implementation of terahertz (THz) quantum cascade lasers (QCLs) for high-resolution absorption spectroscopy on plasmas. Absolute densities of ground state atomic oxygen were directly obtained by using the fine structure transition at approximately 4.75 THz.

A self-consistent fluid model has been successfully developed and employed to model an electron cyclotron resonance driven hydrogen plasma at low pressure. This model has enabled key insights to be made on the mutual interaction of microwave propagation, power density, plasma generation, and species transport at conditions where the critical plasma density is exceeded. The model has been verified by two experimental methods.

Absolute ground state atomic hydrogen densities were measured, by utilisation of two-photon absorption laser induced fluorescence (TALIF), in a low pressure electron cyclotron resonance plasma as a function of nitrogen admixtures - 0 to 5000 ppm. At nitrogen admixtures of 1500 ppm and higher the spectral distribution of the fluorescence changes from a single Gaussian to a double Gaussian distribution; this is due to a separate, nascent, contribution arising from the photolysis of an ammonia molecule.